Practice question
Question
A gas at 3 atm and 600 K has a density of 0.96 kg m⁻³. What is its molecular mass? (R = 8.31 J mol⁻¹ K⁻¹, 1 atm = 1.01 × 10⁵ Pa)
Explanation
**Charles' law** V₁/T₁ = V₂/T₂ at constant pressure, volume proportional to absolute temperature (K), Gay-Lussac P₁/T₁ = P₂/T₂ at constant volume, Boyle's law P₁V₁ = P₂V₂ at constant temperature, combined ideal gas law P V = n R T, R=8.314 J/mol·K. For V₁=24 L T₁=300 K T₂=600 K, V₂= V₁ T₂/T₁=48 L, volume doubles when T doubles at constant P. P = (ρ R T)/(M), M = (ρ R T)/(P).P = 3 × 1.01 × 10⁵ = 3.03 × 10⁵ Pa.M = (0.96 × 8.31 × 600)/(3.03 × 10⁵) = 0.0158 kg/mol ≈ 15.8 g/mol ≈ 16 g/mol. Substituting values gives 16 g/mol, which matches
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