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Electronic Configuration and Types of Elements - s p d f Blocks

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29 questions

Which element in group 2 has the highest second ionization enthalpy?

Second ionization enthalpy for group 2 elements involves removing an electron from X+ (noble gas-like). Be⁺ (smallest size) has the highest value due to greater nuclear attraction.

Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Electronic Configuration and Types of Elements - s p d f Blocks

Which group 16 element forms a hydride with the lowest boiling point?

Boiling points of group 16 hydrides increase with molecular weight, except for H₂O (hydrogen bonding). H₂S has the lowest boiling point among H₂O, H₂S, H₂Se, and H₂Te due to weak intermolecular forces.

Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Electronic Configuration and Types of Elements - s p d f Blocks

Which element in the third period has the highest fourth ionization enthalpy?

Fourth ionization enthalpy peaks when removing an electron from a stable X³⁺ ion. Al (after losing three electrons, becomes Al³⁺ with 1s² 2s² 2p⁶) has the highest value in period 3.

Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Electronic Configuration and Types of Elements - s p d f Blocks

Which element has the ground state electronic configuration 1s² 2s² 2p⁶ 3s² 3p⁶ 3d⁵ 4s¹?

This configuration (Z=24) corresponds to Cr, an exception due to the stability of half-filled 3d⁵, unlike Mn (3d⁵ 4s²), Fe (3d⁶ 4s²), or Co (3d⁷ 4s²).

Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Electronic Configuration and Types of Elements - s p d f Blocks

Which element in group 16 has the highest tendency to exhibit a +6 oxidation state?

The +6 oxidation state is most stable for S (e.g., in SO₃) due to its balance of size and electronegativity, unlike O, Se, or Te, where it’s less common or stable.

Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Electronic Configuration and Types of Elements - s p d f Blocks

Which ion among the following isoelectronic species with 18 electrons has the highest polarizing power?

For isoelectronic species (18 electrons), polarizing power increases with charge and decreases with size. Sc³⁺ (Z=21, +3) has the highest polarizing power compared to K+, Ca²⁺, or Cl⁻.

Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Electronic Configuration and Types of Elements - s p d f Blocks