The pH of human blood is about:
Human blood pH is tightly regulated between 7.35-7.45 by bicarbonate, phosphate and protein buffers plus respiratory and renal compensation. Slight acidity arises from dissolved CO2 forming carbonic acid. Value 7.4 optimizes enzyme activity, oxygen transport and hemoglobin Bohr effect physiologically.
Ref: Hall, Guyton and Hall Textbook of Medical Physiology, 14th Edition, Chapter 30 Acid-Base Regulation of Blood pH, discusses blood pH homeostasis at 7.4 maintained by bicarbonate buffer respiratory renal compensation and optimal enzymatic function, published by Elsevier Saunders Philadelphia.