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Fundamental Concepts - Reaction Mechanism - Fission and Reaction Intermediates

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29 questions

In Lassaigne’s test, the presence of nitrogen gives a Prussian blue color due to the formation of which compound?

In Lassaigne’s test, nitrogen forms Fe₄[Fe(CN)₆]₃ (ferric ferrocyanide) with Fe³⁺, producing the Prussian blue color.

Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Fundamental Concepts - Reaction Mechanism - Fission and Reaction Intermediates

Which free radical is most stable if formed from CH₃CH₂CH₂CH₂CH₃ via homolytic cleavage?

Homolytic cleavage at CH₂ forms CH₃CH₂CH·CH₂CH₃ (secondary radical), more stable than primary due to hyperconjugation.

Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Fundamental Concepts - Reaction Mechanism - Fission and Reaction Intermediates

Which carbocation formed from CH₃CH₂CH(Cl)CH₃ via heterolytic cleavage is stabilized by hyperconjugation after a possibl

Cleavage at C-Cl forms CH₃CH₂CH⁺CH₃ (secondary). Hyperconjugation with adjacent C-H bonds stabilizes it.

Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Fundamental Concepts - Reaction Mechanism - Fission and Reaction Intermediates

In Lassaigne’s test, the presence of iodine is confirmed by the formation of a precipitate of what color with silver nit

Iodine forms NaI in Lassaigne’s test, which reacts with AgNO₃ to form a yellow precipitate of AgI.

Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Fundamental Concepts - Reaction Mechanism - Fission and Reaction Intermediates