What is the major product when benzene is treated with chlorine in the presence of AlCl₃ ?
Benzene undergoes electrophilic substitution with chlorine to form chlorobenzene. This follows from NCERT principle where relation explains outcome clearly for students.
Ref: NCERT Chemistry Textbook for Class XI and XII, Chapter: Hydrocarbons, Topic: Aromatic hydrocarbons, benzene as example, Hückel rule and aromaticity.