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#magnesium

9 public questions tagged with this topic.

In electrolysis of molten MgCl₂, 0.24 g of Mg (atomic mass 24 g/mol) is deposited. What volume of Cl₂ gas (STP) is produ

Cathode: Mg²⁺ + 2e⁻ → Mg . Moles = (0.24/24) = 0.01 mol , Charge = 0.01 × 2 × 96500 = 1930 C . Anode: 2Cl⁻ → Cl₂ + 2e⁻ . Moles Cl₂ = 0.01 mol , Volume = 0.01 × 22.4 = 0.224 L .

Ref: NCERT Class 12 Chemistry > Chapter 2: Electrochemistry > Topic: Electrolytic Cells and Electrolysis and Faraday's Laws

Metal ion required for DNA polymerase activity is

DNA synthesis proceeds via nucleophilic attack of primer 3' hydroxyl on alpha-phosphate of incoming dNTP. Two Mg2+ ions, coordinated by conserved aspartate residues in polymerase active site, orchestrate catalysis. One ion activates 3'OH lowering pKa for attack, the other stabilizes pentacovalent transition state and facilitates pyrophosphate departure. Without Mg2+, phosphodiester bond formation stalls entirely. This two-metal mechanism explains why chelators like EDTA inhibit polymerization, why Ca2+ fails to substitute effectively, and why high fidelity polymerases absolutely require magnes

Ref: Alberts et al., Molecular Biology of the Cell, 7th ed., Chapter 5: DNA Replication Mechanisms, Two-metal-ion catalysis