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Question

A gas has a density of 0.8 kg m⁻³ at 1 atm and 300 K. What is its molecular mass? (R = 8.31 J mol⁻¹ K⁻¹, 1 atm = 1.01 × 10⁵ Pa)

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Explanation

**Temperature dependence of RMS speed** v_rms ∝ √T, doubling T increases v_rms by √2≈1.414, e.g., at 300 K v_rms for O₂ ≈483 m/s, at 600 K ≈683 m/s, illustrating kinetic theory relation between temperature and molecular motion, average kinetic energy ½ m v_rms² =3/2 k_B T. P = (ρ R T)/(M), so M = (ρ R T)/(P).M = (0.8 × 8.31 × 300)/(1.01 × 10⁵) = 0.01975 kg/mol = 19.75 g/mol ≈ 20 g/mol . Substituting values gives 20 g/mol, which matches expected kinetic theory result, confirming mean free path λ = 1/(√2 n π d²), ideal gas law P V = n R T

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