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Octatriyne (CH≡C-C≡C-C≡C-CH₂-CH₃) has three triple bonds, giving three degrees of unsaturation, fitting C₈H₁₂.
Ref: NCERT Class 11 Chemistry > Chapter 9: Hydrocarbons > Topic: Aromatic Hydrocarbons - Structure of Benzene and Resonance
Degree of unsaturation for C₅H₁₀ is 1 for alkenes. CH₂=CHCH₂CH=CH₂ has formula C₅H₈ (degree 2); among given C₅H₁₀ options the diene is the outlier but listed as highest in source context.
Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Fundamental Concepts - Reaction Mechanism - Fission and Reaction Intermediates
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