Which of the following has the highest first ionization enthalpy among the third period elements?
First ionization enthalpy increases across a period. Among Na, Mg, Si, and Ar, Ar (group 18, period 3) has the highest value due to its stable noble gas configuration.
Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Periodic Trends - Atomic Radii Ionic Radii and Ionization Enthalpy