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For the same metal and ligands, the tetrahedral splitting ( Δ_t ) is 4/9 of the octahedral splitting ( Δ_o ), due to fewer ligands and different geometry.
Ref: NCERT Chemistry Textbook for Class XI and XII, Chapter: Coordination Compounds and d Block Elements, Topic: Colour of [Ti(H₂O)₆]³⁺, d-d transition, crystal field theory.
[Ni(NH₃)4]2+ has 4 NH₃ ligands, giving a coordination number of 4. Others like [Co(NH₃)6]3+ (6) and [Fe(CN)6]4− (6) have higher coordination numbers.
Ref: NCERT Class 12 Chemistry > Chapter 5: Coordination Compounds > Topic: Werner's Theory and Definitions - Ligands Coordination Number
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