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Aniline (C₆H₅NH₂) undergoes electrophilic substitution with Br₂ in water, forming 2,4,6-tribromoaniline and decolorizing bromine, as per the PDF.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Physical Properties, Basic Character and Solubility
Excess NH₃ reacts with CH₃CH₂CH₂Br via nucleophilic substitution to form the primary amine CH₃CH₂CH₂NH₂ (propylamine).
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Nucleophilic Substitution Reactions - SN1 and SN2 Mechanisms
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