Relation between wavelength of photon and electron of same energy is:
Photon λ=hc/E, electron λ=h/√(2mE), photon wavelength larger for same E? Actually electron smaller.
Ref: NCERT Physics Class 12 Chapter 13 Nuclei
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Photon λ=hc/E, electron λ=h/√(2mE), photon wavelength larger for same E? Actually electron smaller.
Ref: NCERT Physics Class 12 Chapter 13 Nuclei
**Work function** Φ minimum energy to escape, for Φ=2.2 eV λ₀=1240/2.2=563.6 nm, Φ=3.0 eV threshold frequency f₀=Φ/h=3×1.6×10⁻¹⁹/6.63×10⁻³⁴=7.24×10¹⁴ Hz, stopping potential V₀ = (h f - Φ)/e, for 0.7 V K_max=0.7 eV, for 1.5 V K_max=1.5 eV, intensity increase increases photocurrent not K_max, frequency below threshold no emission regardless of intensity. E = (h c/λ) = (1240/300) ≈ 4.13 eV . Kₘₐₓ = e V₀ = 1.5 eV . Φ₀ = E - Kₘₐₓ = 4.13 - 1.5 = 2.63 eV . Applying E = h f = h c/λ, p = h/λ, K_max = h f - Φ, Φ = h f₀ = h c/λ₀,
Ref: NCERT > Physics Book > Dual Nature of Matter > Photoelectric Effect - Work Function and Threshold
**Thomson's plum pudding model** positive charge uniformly distributed in sphere with electrons embedded, positive charge spread, fails to explain large angle scattering observed. Bohr's model introduces stationary orbits with quantized angular momentum L = n h/2π, physical basis de Broglie standing wave condition 2πr = n λ, circumference fits n wavelengths, explains line spectrum. Δ E = 0.66 eV = 1.056 × 10⁻¹⁹ J . λ = (hc/Δ E) = (6.6 × 10⁻³⁴ × 3 × 10⁸/1.056 × 10⁻¹⁹) ≈ 1.875 × 10⁻⁶ m . Using E_n = -13.6/n² eV, r_n = n² a₀, L = n h/2π, R = R₀ A^¹/³, BE = Δm
Ref: NCERT > Physics Book > Atoms and Nuclei > Atomic Models - Rutherford, Thomson and Bohr
**Bohr's stationary orbits** defined by angular momentum quantization L = n ħ, ħ = h/2π, n=1 ground state, electron in these orbits does not radiate despite acceleration, contrary to classical EM theory which predicts atom collapse due to energy loss via radiation, Bohr postulates to explain observed stability and discrete spectra. Δ E = 10.2 eV = 1.632 × 10⁻¹⁸ J . λ = (hc/Δ E) = (6.6 × 10⁻³⁴ × 3 × 10⁸/1.632 × 10⁻¹⁸) ≈ 1.21 × 10⁻⁷ m . Using E_n = -13.6/n² eV, r_n = n² a₀, L = n h/2π, R = R₀ A^¹/³, BE = Δm c² and 1
Ref: NCERT > Physics Book > Atoms and Nuclei > Atomic Models - Rutherford, Thomson and Bohr
E = hc/λ = 6.626×10⁻¹⁹ J. W₀ = E - KE = 4.626×10⁻¹⁹ J.
Ref: NCERT Class 11 Chemistry > Chapter 2: Structure of Atom > Topic: Shapes of Orbitals - s p d f and Nodes and Radial Probability
E = hc/λ ≈ 7.951×10⁻¹⁹ J. KE = h²/(2mλ²) ≈ 2.412×10⁻¹⁹ J. W₀ = E - KE ≈ 5.539×10⁻¹⁹ J.
Ref: NCERT Class 11 Chemistry > Chapter 2: Structure of Atom > Topic: Quantum Mechanical Model - de Broglie Heisenberg and Schrodinger
ΔE = 10.2 eV. λ = hc/ΔE ≈ 121.7 nm.
Ref: NCERT Class 11 Chemistry > Chapter 2: Structure of Atom > Topic: Developments Leading to Bohr Model - Electromagnetic Radiation and Spectrum
For C⁵⁺ (Z=6), ΔE = 91.8 eV. λ = hc/ΔE ≈ 13.53 nm.
Ref: NCERT Class 11 Chemistry > Chapter 2: Structure of Atom > Topic: Developments Leading to Bohr Model - Electromagnetic Radiation and Spectrum
For He⁺ (Z=2), wavenumber ν̄ = Z² RH (1/n₁² - 1/n₂²) = 4 × 1.097×10⁷ (1/1² - 1/3²) ≈ 3.901×10⁷ m⁻¹. λ = 1/ν̄ ≈ 2.563×10⁻⁸ m = 25.63 nm.
Ref: NCERT Class 11 Chemistry > Chapter 2: Structure of Atom > Topic: Developments Leading to Bohr Model - Electromagnetic Radiation and Spectrum
For Li²⁺ (Z=3), ΔE = 25.704 eV. λ ≈ 48.34 nm.
Ref: NCERT Class 11 Chemistry > Chapter 2: Structure of Atom > Topic: Atomic Models - Thomson Rutherford and Bohr Model
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