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2,4,6-Trinitrophenol (picric acid) is the most acidic due to three electron-withdrawing -NO₂ groups stabilizing the phenoxide ion via resonance and inductive effects.
Ref: NCERT Class 12 Chemistry > Chapter 7: Alcohols, Phenols and Ethers > Topic: Physical Properties and Acidity of Alcohols and Phenols
2-Nitrophenol is steam volatile due to intramolecular hydrogen bonding between -OH and -NO₂, reducing intermolecular forces, unlike 4-nitrophenol.
Ref: NCERT Class 12 Chemistry > Chapter 7: Alcohols, Phenols and Ethers > Topic: Chemical Reactions of Alcohols - Dehydration Oxidation Esterification
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