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For the same metal and ligands, the tetrahedral splitting ( Δ_t ) is 4/9 of the octahedral splitting ( Δ_o ), due to fewer ligands and different geometry.
Ref: NCERT Chemistry Textbook for Class XI and XII, Chapter: Coordination Compounds and d Block Elements, Topic: Colour of [Ti(H₂O)₆]³⁺, d-d transition, crystal field theory.
[Co(CN)6]3− (Co₃+, d6) with strong field CN− is low spin (t2g6), with 0 unpaired electrons.
Ref: NCERT Class 12 Chemistry > Chapter 5: Coordination Compounds > Topic: Isomerism - Optical Isomerism and Linkage Ionisation Solvate
[Cr(H₂O)3Cl₃] (octahedral, [Ma₃b3]) can have a facial (fac) isomer where 3 Cl− ligands occupy one face.
Ref: NCERT Class 12 Chemistry > Chapter 5: Coordination Compounds > Topic: Isomerism - Optical Isomerism and Linkage Ionisation Solvate
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