Why is carbon an insulator while silicon and germanium are semiconductors?
Carbon (diamond) has a large energy gap (5.4 eV), preventing electron excitation at room temperature, while Si (1.1 eV) and Ge (0.7 eV) have smaller gaps, allowing thermal excitation and conduction.
Ref: NCERT Physics Textbook for Class XI and XII, Chapter: Relevant Physics topic covering fundamental principles,