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[Ni(CN)4]2− (Ni₂+, d8) with strong field CN− adopts square planar geometry, unlike tetrahedral with weak field ligands.
Ref: NCERT Class 12 Chemistry > Chapter 5: Coordination Compounds > Topic: Crystal Field Theory - CFT and Crystal Field Splitting and CFSE
[Co(CN)6]3− has CN−, stronger field ligand than NH₃.
Ref: NCERT Class 12 Chemistry > Chapter 5: Coordination Compounds > Topic: Colour and Magnetic Properties and Stability and Importance
The hexacyanoferrate(II) ion has octahedral geometry with d 2 sp 3 hybridization.
Ref: NCERT Class 12 Chemistry > Chapter 4: d and f Block Elements > Topic: Oxidation States and Colour and Magnetic Properties of d-Block
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