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Butan-1-amine (CH₃CH₂CH₂CH₂NH₂) has the longest chain and strong hydrogen bonding, giving it the highest boiling point, as per the PDF’s physical properties.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Reaction with Nitrous Acid and Diazonium Salts - Part 1
Glycerol (CH₂OH-CHOH-CH₂OH) has three -OH groups, forming extensive hydrogen bonding, which increases its boiling point compared to ethanol with one -OH group.
Ref: NCERT Class 12 Chemistry > Chapter 7: Alcohols, Phenols and Ethers > Topic: Classification and Nomenclature and Structures of Alcohols Phenols Ethers
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