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Ammonolysis of CH₃CH₂Cl with excess NH₃ favors the formation of the primary amine CH₃CH₂NH₂ (ethylamine), as per the PDF’s preparation methods.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Reaction with Nitrous Acid and Diazonium Salts - Part 2
Methylamine (CH₃NH₂) is formed directly from CH₃Cl and NH₃ in one step via ammonolysis, as per the PDF’s preparation methods.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Reaction with Nitrous Acid and Diazonium Salts - Part 2
Benzyl chloride (C₆H₅CH₂Cl) with excess NH₃ forms benzylamine (C₆H₅CH₂NH₂) via ammonolysis, as per the PDF’s preparation methods.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Reaction with Nitrous Acid and Diazonium Salts - Part 2
Excess NH₃ reacts with CH₃CH₂CH₂Br via nucleophilic substitution to form the primary amine CH₃CH₂CH₂NH₂ (propylamine).
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Nucleophilic Substitution Reactions - SN1 and SN2 Mechanisms
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