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4-Nitrophenol has intermolecular hydrogen bonding, increasing intermolecular forces and reducing volatility, while 2-nitrophenol has intramolecular hydrogen bonding, making it more volatile.
Ref: NCERT Class 12 Chemistry > Chapter 7: Alcohols, Phenols and Ethers > Topic: Chemical Reactions of Alcohols - Dehydration Oxidation Esterification
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