Practice question

**Bohr energy levels** E_n = -13.6/n² eV for hydrogen, negative indicating bound state, total energy = -13.6 eV ground state n=1, -3.4 eV n=2, -1.51 eV n=3, etc., photon energy for transition n_i → n_f is ΔE =13.6(1/n_f² -1/n_i²) eV, wavelength λ = hc/ΔE, h=6.6×10⁻³⁴ J·s, c=3×10⁸ m/s. Emission line spectrum characterized by discrete wavelengths because energy levels discrete. De Broglie’s hypothesis supports quantization by proposing standing waves, not continuous waves, which fit an integer number of wavelengths into the orbit. Using E_n = -13.6/n² eV, r_n = n² a₀, L = n h/2π, R = R₀ A^¹/³, BE = Δm c² and 1 u