Practice question
Question
A gas at 3 atm and 600 K has a volume of 15 litres. If the pressure decreases to 1.5 atm at constant temperature, what is the new volume?
Explanation
**RMS speed** v_rms = √(3 R T/M) = √(3 k_B T/m) where M molar mass (kg/mol), m molecular mass (kg), k_B=1.38×10⁻²/³ J/K, R=8.314 J/mol·K, T absolute temperature (K). Proportional to √T and 1/√M, lighter gases faster at same T, e.g., H₂ faster than O₂, temperature increase raises v_rms as √T. Boyle’s law: P₁ V₁ = P₂ V₂.P₁ = 3 atm, V₁ = 15 litres, P₂ = 1.5 atm.V₂ = (P₁ V₁)/(P₂) = (3 × 15)/(1.5) = 30 litres. Substituting values gives 30 litres, which matches expected kinetic theory result, confirming mean free path λ = 1/(√2 n π d²), ideal gas law P V =
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