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This is a Finkelstein reaction, where NaI in acetone substitutes Cl in CH₃CH₂CH₂Cl to form CH₃CH₂CH₂I (1-iodopropane).
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Physical Properties - Boiling Point Dipole Moment Solubility
CN⁻ (cyanide ion) is a strong nucleophile that displaces Br⁻ in a substitution reaction to form CH₃CH₂CN (propanenitrile).
Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Isomerism - Stereoisomerism - Geometrical and Optical Isomerism
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