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#nitrogen detection

2 public questions tagged with this topic.

In Lassaigne’s test, an organic compound containing nitrogen and chlorine gives a Prussian blue color but no silver hali

Prussian blue indicates nitrogen (forming NaCN), but no AgCl precipitate suggests chlorine is not ionic or not extracted as NaCl, possibly due to covalent bonding not broken by sodium fusion.

Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Isomerism - Stereoisomerism - Geometrical and Optical Isomerism

In Lassaigne’s test, the presence of nitrogen gives a Prussian blue color due to the formation of which compound?

In Lassaigne’s test, nitrogen forms Fe₄[Fe(CN)₆]₃ (ferric ferrocyanide) with Fe³⁺, producing the Prussian blue color.

Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Fundamental Concepts - Reaction Mechanism - Fission and Reaction Intermediates