The boiling point of CH₃CH₂NH₂ is higher than CH₃CH₃ because of:
Ethylamine (CH₃CH₂NH₂) forms hydrogen bonds, unlike ethane (CH₃CH₃), which relies on weak van der Waals forces, as per the PDF’s physical properties.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Reaction with Nitrous Acid and Diazonium Salts - Part 1