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Cleavage at CH₂Cl forms CH₃CH₂CH₂CH₂CH₂⁺ (primary). A hydride shift to CH₃CH₂CH₂CH⁺CH₃ (secondary) increases stability via hyperconjugation.
Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Electronic Effects - Inductive Mesomeric Hyperconjugation and Resonance
The primary carbocation CH₃CH₂CH₂CH₂⁺ can undergo a hydride shift to form CH₃CH⁺CH₂CH₃ (secondary), which is more stable due to hyperconjugation.
Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Electronic Effects - Inductive Mesomeric Hyperconjugation and Resonance
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