The bond angle around nitrogen in (CH₃CH₂)₂NH is closest to:
Diethylamine ((CH₃CH₂)₂NH) has sp3 hybridized nitrogen with a lone pair, giving a bond angle slightly less than 109.5° (around 107°-108°), as per the PDF’s structure.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Chemical Reactions - Alkylation, Acylation and Electrophilic Substitution