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Free radical halogenation of propane ( CH₃CH₂CH₃ ) with Cl₂ forms CH₃CHClCH₃ (2-chloropropane) as one product.
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Classification and Nomenclature and Isomerism of Haloalkanes
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