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[Cr(H₂O)6]3+ (Cr₃+, d3) undergoes d-d transitions, absorbing visible light.
Ref: NCERT Class 12 Chemistry > Chapter 5: Coordination Compounds > Topic: Isomerism - Geometrical Isomerism in Coordination Compounds
[Cu(H₂O)4]2+ (Cu₂+, d9) undergoes a d-d transition in its square planar field, absorbing visible light (blue color), unlike [Ni(CO)4] (d10, no transition).
Ref: NCERT Class 12 Chemistry > Chapter 5: Coordination Compounds > Topic: Crystal Field Theory - CFT and Crystal Field Splitting and CFSE
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