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#qualitative analysis

13 public questions tagged with this topic.

In Lassaigne’s test, an organic compound containing nitrogen and chlorine gives a Prussian blue color but no silver hali

Prussian blue indicates nitrogen (forming NaCN), but no AgCl precipitate suggests chlorine is not ionic or not extracted as NaCl, possibly due to covalent bonding not broken by sodium fusion.

Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Isomerism - Stereoisomerism - Geometrical and Optical Isomerism

In Lassaigne’s test, the presence of sulphur is confirmed by the formation of a violet color with which reagent?

Sulphur forms Na₂S in Lassaigne’s test, which reacts with sodium nitroprusside to give a violet-colored complex, Na₄[Fe(CN)₅NOS].

Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Isomerism - Stereoisomerism - Geometrical and Optical Isomerism

In Lassaigne’s test, the presence of iodine is confirmed by the formation of a precipitate of what color with silver nit

Iodine forms NaI in Lassaigne’s test, which reacts with AgNO₃ to form a yellow precipitate of AgI.

Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Fundamental Concepts - Reaction Mechanism - Fission and Reaction Intermediates

In Lassaigne’s test, an organic compound produces a blood-red color with FeCl₃ but no violet color with sodium nitroprus

Blood-red color with FeCl₃ indicates nitrogen and sulphur together (NaSCN), while no violet color with sodium nitroprusside suggests sulphur alone isn’t detected, but the former confirms both.

Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Classification and Nomenclature of Organic Compounds - IUPAC