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SOCl₂ with pyridine converts ethanol to ethyl chloride, releasing SO₂ and HCl gases; SO₂ is the key gaseous byproduct.
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Nature of C-X Bond and Methods of Preparation
SOCl₂ with pyridine converts 2-butanol ( CH₃CH₂CHOHCH₃ ) to 2-chlorobutane ( CH₃CH₂CHClCH₃ ) via substitution.
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Classification and Nomenclature and Isomerism of Haloalkanes
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