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Cleavage at C-Cl forms CH₃CH₂CH⁺CH₃ (secondary). Hyperconjugation with adjacent C-H bonds stabilizes it.
Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Fundamental Concepts - Reaction Mechanism - Fission and Reaction Intermediates
Carbocations are stabilized by hyperconjugation, where adjacent C-H bonds donate electron density to the empty p-orbital.
Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Fundamental Concepts - Reaction Mechanism - Fission and Reaction Intermediates
(CH₃)₂CH⁺ (secondary) is more stable than primary carbocations due to hyperconjugation with adjacent C-H bonds.
Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Electronic Effects - Inductive Mesomeric Hyperconjugation and Resonance
In CH₃CH₂C(=O)CH₂CH₃, the carbon in CH₂ adjacent to C=O (second carbon) forms CH₃CH⁺CH₂C(=O)CH₃, stabilized by hyperconjugation from CH₃.
Ref: NCERT Class 11 Chemistry > Chapter 8: Organic Chemistry - Some Basic Principles and Techniques > Topic: Electronic Effects - Inductive Mesomeric Hyperconjugation and Resonance
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