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Alkenes react with hydrogen halides (e.g., HBr ) via electrophilic addition to form alkyl halides. CH₃CH₂CH₂Br can be made from CH₃CH=CH₂ with HBr (peroxide conditions).
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Classification and Nomenclature and Isomerism of Haloalkanes
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