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In the presence of peroxides, HBr adds to propene anti-Markovnikov, with Br attaching to the less substituted carbon, forming CH₃CH₂CH₂Br .
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Physical Properties - Boiling Point Dipole Moment Solubility
For 1-butene ( CH₂=CHCH₂CH₃ ), HBr adds via Markovnikov's rule, forming CH₃CHBrCH₂CH₃ (2-bromobutane).
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Classification and Nomenclature and Isomerism of Haloalkanes
For 2-pentene ( CH₃CH=CHCH₂CH₂CH₃ ), HBr adds via Markovnikov's rule, forming CH₃CHBrCH₂CH₂CH₃ (2-bromopentane).
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Classification and Nomenclature and Isomerism of Haloalkanes
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