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Free radical chlorination of propane ( CH₃CH₂CH₃ ) with Cl₂ in light substitutes Cl at C₁ or C₂, forming CH₃CH₂CH₂Cl and CH₃CHClCH₃ .
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Polyhalogen Compounds - Chloroform Iodoform DDT Freons
Pentane ( CH₃CH₂CH₂CH₂CH₃ ) on chlorination favors the secondary position (C₃), forming CH₃CH₂CHClCH₂CH₃ (3-chloropentane).
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Polyhalogen Compounds - Chloroform Iodoform DDT Freons
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