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Total volume = 3V, [X-] = (0.06 × 2V/3V) = 0.04 M , pKa = 4.7 , pH = 4.7 + log (0.04/0.04) = 4.7 .
Ref: NCERT Class 11 Chemistry > Chapter 6: Equilibrium > Topic: Relationship Between Kp Kc and Factors Affecting Equilibrium - Le Chatelier
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