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A benzylic halide has the halogen on a carbon directly attached to a benzene ring. C₆H₅CH(CH₃)Cl (1-chloroethylbenzene) is benzylic.
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Polyhalogen Compounds - Chloroform Iodoform DDT Freons
A benzylic halide has the halogen on a carbon directly attached to a benzene ring. C₆H₅CH₂Cl (benzyl chloride) fits this definition.
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Nature of C-X Bond and Methods of Preparation
C₆H₅CHClCH₃ (1-chloro-1-phenylethane) has Cl on a carbon attached to a benzene ring (benzylic) and two carbons (secondary).
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Classification and Nomenclature and Isomerism of Haloalkanes
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