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Electrophilic substitution of benzene with Cl₂ and FeCl₃ in the dark forms C₆H₄Cl₂ (1,4-dichlorobenzene) efficiently.
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Nature of C-X Bond and Methods of Preparation
Benzene ( C₆H₆ ) with excess Cl₂ in sunlight forms hexachlorocyclohexane ( C₆H₆Cl₆ ), which has 6 chlorine atoms.
Ref: NCERT Class 12 Chemistry > Chapter 6: Haloalkanes and Haloarenes > Topic: Elimination Reactions and Reaction with Metals and Other Reactions
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