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Methylamine (CH₃NH₂, 1C) has two N-H bonds for hydrogen bonding relative to one carbon, giving the highest solubility per carbon, as per the PDF.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Reaction with Nitrous Acid and Diazonium Salts - Part 1
Primary amines like CH₃CH₂NH₂ have N-H bonds that can form hydrogen bonds with water, enhancing solubility, as per the PDF’s physical properties.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Reaction with Nitrous Acid and Diazonium Salts - Part 1
Methylamine (CH₃NH₂) has the smallest alkyl group, allowing maximum hydrogen bonding with water, as per the PDF’s physical properties.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Reaction with Nitrous Acid and Diazonium Salts - Part 1
Butan-1-amine (CH₃CH₂CH₂CH₂NH₂) has the longest chain and strong hydrogen bonding, giving it the highest boiling point, as per the PDF’s physical properties.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Reaction with Nitrous Acid and Diazonium Salts - Part 1
Hydrogen bonding decreases from primary (two N-H) to secondary (one N-H) to tertiary (no N-H), as per the PDF’s physical properties.
Ref: NCERT Class 12 Chemistry > Chapter 13: Amines > Topic: Physical Properties, Basic Character and Solubility
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