Practice question
Question
The rms speed of oxygen molecules is 482 m/s at 300 K. What is the rms speed of methane molecules at the same temperature? (Molecular mass: O₂ = 32 u, CH₄ = 16 u)
Explanation
**Molecular mass and density** relation ρ = P M/(R T) allows density calculation, ideal gas law also P = n k_B T where n number density, molecular mass determines mass per molecule, density increases with pressure and decreases with temperature, inverse T dependence. v_rms ∝ (1)/(√(m)), v_CH₄v_O₂ = √(m_O)₂m_CH₄.v_CH₄482 = √((32)/(16)) = √(2) ≈ 1.414.v_CH₄ = 482 × 1.414 ≈ 682 m/s. Substituting values gives 682 m/s, which matches expected kinetic theory result, confirming mean free path λ = 1/(√2 n π d²), ideal gas law P V = n R T and v_rms = √(3 R T/M) relations.
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