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Question

A gas at 1.5 atm and 300 K has a volume of 24 litres. If the temperature increases to 600 K at constant pressure, what is the new volume?

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Explanation

**Molecular diameter from mean free path** uses λ =1/(√2 n π d²), solving d = √(1/(√2 n π λ)). At higher pressure n ∝ P, λ ∝1/P, so doubling P halves λ, illustrating pressure dependence of collision distance. Charles’ law: (V₁)/(T₁) = (V₂)/(T₂).V₁ = 24 litres, T₁ = 300 K, T₂ = 600 K.V₂ = V₁ × (T₂)/(T₁) = 24 × (600)/(300) = 48 litres. Substituting values gives 48 litres, which matches expected kinetic theory result, confirming mean free path λ = 1/(√2 n π d²), ideal gas law P V = n R T and v_rms = √(3 R T/M) relations.

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