Practice question
Question
A gas has a C_v of 12.5 J mol⁻¹ K⁻¹. What is the ratio of specific heats (gamma)? (R = 8.31 J mol⁻¹ K⁻¹)
Explanation
**RMS speed** v_rms = √(3 R T/M) = √(3 k_B T/m) where M molar mass (kg/mol), m molecular mass (kg), k_B=1.38×10⁻²/³ J/K, R=8.314 J/mol·K, T absolute temperature (K). Proportional to √T and 1/√M, lighter gases faster at same T, e.g., H₂ faster than O₂, temperature increase raises v_rms as √T. C_p = C_v + R = 12.5 + 8.31 = 20.81 J mol⁻¹ K⁻¹.γ = (C_p)/(C_v) = (20.81)/(12.5) ≈ 1.67. Substituting values gives 1.67, which matches expected kinetic theory result, confirming mean free path λ = 1/(√2 n π d²), ideal gas law P V = n R T and v_rms = √(3 R T/M) relations.
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