Practice question
Question
A solid has a molar specific heat capacity of 25 J mol⁻¹ K⁻¹ at room temperature. How many degrees of freedom does each atom have?
Explanation
**RMS speed** v_rms = √(3 R T/M) = √(3 k_B T/m) where M molar mass (kg/mol), m molecular mass (kg), k_B=1.38×10⁻²/³ J/K, R=8.314 J/mol·K, T absolute temperature (K). Proportional to √T and 1/√M, lighter gases faster at same T, e.g., H₂ faster than O₂, temperature increase raises v_rms as √T. For a solid, C = f × (R)/(2) × N_A = f × (R)/(2) × 1 = f × (R)/(2).Given C = 25 J mol⁻¹ K⁻¹, R = 8.31 J mol⁻¹ K⁻¹.25 = f × (8.31)/(2), f = (25 × 2)/(8.31) ≈ 6. Substituting values gives 6, which matches expected kinetic theory result, confirming mean
Discussion
Comments
Please log in to join the discussion.
Login to commentNo comments yet. Be the first to start the discussion.