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Question

What is the molar specific heat capacity at constant pressure for a diatomic gas if C_v = 20.75 J mol⁻¹ K⁻¹ and R = 8.3 J mol⁻¹ K⁻¹ ?

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Explanation

**Isochoric process** constant volume ΔV=0, work W=0, first law ΔU = Q, all heat goes to internal energy, P/T = constant from ideal gas law P V = n R T at constant V, pressure proportional to temperature, P₁/T₁ = P₂/T₂, e.g., heating gas in rigid container pressure rises proportionally to T. C_p - C_v = R . C_p = C_v + R = 20.75 + 8.3 = 29.05 J mol⁻¹ K⁻¹ ≈ 29.1 J mol⁻¹ K⁻¹ . Using first law ΔU = Q - W, W = ∫ P dV, isobaric W = P ΔV, isothermal W = n R T ln(V₂/V₁), adiabatic P

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