Practice question
Question
A gas has a C_p of 29.8 J mol⁻¹ K⁻¹. What is the ratio of specific heats (gamma)? (R = 8.31 J mol⁻¹ K⁻¹)
Explanation
**Ideal gas equation** P V = n R T = (m/M) R T, density ρ = m/V = P M/(R T), molecular mass M (kg/mol), P pressure (Pa), T temperature (K). At given P,T density proportional to M, heavier gases denser, e.g., at 1.5 atm 300 K V=24 L n= P V/(R T)=1.5×1.013×10⁵×0.024/(8.314×300)≈1.46 mol. C_v = C_p - R = 29.8 - 8.31 = 21.49 J mol⁻¹ K⁻¹.γ = (C_p)/(C_v) = (29.8)/(21.49) ≈ 1.39 ≈ 1.40. Substituting values gives 1.40, which matches expected kinetic theory result, confirming mean free path λ = 1/(√2 n π d²), ideal gas law P V = n R T
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