Practice question
Question
What is the osmotic pressure of a solution containing 1.11 g of CaCl₂ in 300 mL of water at 27°C, assuming complete dissociation? ( R = 0.0821 L atm/mol K, Molar mass of CaCl₂ = 111 g/mol, i = 3 )
Explanation
Given:
What is the osmotic pressure of a solution containing 1.11 g of CaCl₂ in 300 mL of water at 27°C, assuming complete dissociation? ( R = 0.0821 L atm/mol K, Molar mass of CaCl₂ = 111 g/mol, i = 3 )
These values define the system as per NCERT data.
Formula:
Moles of CaCl₂ = 1.11/111 = 0.01 mol.
This is standard NCERT relation.
Substitution & Calculation:
Molarity = 0.01/0.3 = 0.0333 M . Pi = i · C · R · T = 3 × 0.0333 × 0.0821 × 300 = 2.46 atm .
Result:
The computed value matches expected outcome and confirms correct choice as per NCERT.
Discussion
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