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Question

For the process CO(g) + 2H₂(g) → CH₃OH(l) , Δ H = -128 kJ/mol at 298 K, calculate Δ U . ( R = 8.314 J/mol·K )

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Explanation

For CO(g) + 2H₂(g) → CH₃OH(l) , Δ ng = 0 - (1 + 2) = -3 . Then, RT = 8.314 × 298 × 10⁻³ = 2.4776 kJ . Using Δ H = Δ U + Δ ng RT , we get Δ U = Δ H - Δ ng RT = -128 - (-3 × 2.4776) = -128 + 7.4328 = -120.57 kJ/mol .