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E°cell = 0.00 - (-0.14) = 0.14 V . Ecell = 0.14 - (0.059/2) log (0.05/0.1²) = 0.14 + 0.039 = 0.179 V .
Ref: NCERT Class 12 Chemistry > Chapter 2: Electrochemistry > Topic: Nernst Equation and Gibbs Energy and Equilibrium Constant
Boiling point of group 14 tetrachlorides (XCl₄) increases with molecular weight due to stronger London forces. SnCl₄ (Sn, heaviest) has the highest boiling point among C, Si, Ge, and Sn.
Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Nomenclature of Elements with Atomic Number >100
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