The molecularity of the elementary step Cl₂ + H₂ → 2HCl is:
Two molecules collide → molecularity = 2.
Ref: NCERT Class 12 Chemistry > Chapter 3: Chemical Kinetics > Topic: Temperature Dependence - Arrhenius Equation and Activation Energy
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Two molecules collide → molecularity = 2.
Ref: NCERT Class 12 Chemistry > Chapter 3: Chemical Kinetics > Topic: Temperature Dependence - Arrhenius Equation and Activation Energy
k₂ ≈ 6.12 × 10⁻³ s⁻¹.
Ref: NCERT Class 12 Chemistry > Chapter 3: Chemical Kinetics > Topic: Temperature Dependence - Arrhenius Equation and Activation Energy
log 2.25 ≈ 0.352 → Ea ≈ 62.7 kJ mol⁻¹.
Ref: NCERT Class 12 Chemistry > Chapter 3: Chemical Kinetics > Topic: Temperature Dependence - Arrhenius Equation and Activation Energy
t₉₉ / t½ ≈ 6.64 ≈ 7.
Ref: NCERT Class 12 Chemistry > Chapter 3: Chemical Kinetics > Topic: Temperature Dependence - Arrhenius Equation and Activation Energy
Overall order = 2 + 1 = 3.
Ref: NCERT Class 12 Chemistry > Chapter 3: Chemical Kinetics > Topic: Temperature Dependence - Arrhenius Equation and Activation Energy
New rate = 9 × initial rate.
Ref: NCERT Class 12 Chemistry > Chapter 3: Chemical Kinetics > Topic: Temperature Dependence - Arrhenius Equation and Activation Energy
x = 0.8, pA = 1.2. k ≈ 0.00675 s⁻¹.
Ref: NCERT Class 12 Chemistry > Chapter 3: Chemical Kinetics > Topic: Temperature Dependence - Arrhenius Equation and Activation Energy
log 3 → Ea ≈ 79.4 kJ mol⁻¹.
Ref: NCERT Class 12 Chemistry > Chapter 3: Chemical Kinetics > Topic: Temperature Dependence - Arrhenius Equation and Activation Energy
log 2.83 ≈ 0.451 → Ea ≈ 80.3 kJ mol⁻¹.
Ref: NCERT Class 12 Chemistry > Chapter 3: Chemical Kinetics > Topic: Temperature Dependence - Arrhenius Equation and Activation Energy
log 2 → Ea ≈ 52.8 kJ mol⁻¹.
Ref: NCERT Class 12 Chemistry > Chapter 3: Chemical Kinetics > Topic: Temperature Dependence - Arrhenius Equation and Activation Energy
log 3 → Ea ≈ 84.9 kJ mol⁻¹.
Ref: NCERT Class 12 Chemistry > Chapter 3: Chemical Kinetics > Topic: Temperature Dependence - Arrhenius Equation and Activation Energy
Three molecules collide → molecularity = 3.
Ref: NCERT Class 12 Chemistry > Chapter 3: Chemical Kinetics > Topic: Temperature Dependence - Arrhenius Equation and Activation Energy