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Electron Gain Enthalpy and Electronegativity and Valency

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Which group 17 element has the highest electron affinity despite not having the most negative electron gain enthalpy?

Electron affinity is the energy change for X + e⁻ -> X⁻. Cl has the highest electron affinity due to its balance of size and nuclear charge, though F’s electron gain enthalpy is less negative due to repulsion.

Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Electron Gain Enthalpy and Electronegativity and Valency