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Modern Periodic Law and Present Form - Long Form Periodic Table

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29 questions

Which element in group 15 has the highest tendency to form stable compounds in the +3 oxidation state?

The +3 oxidation state becomes more stable down group 15 due to the inert pair effect. Bi forms stable BiCl₃ (+3), more so than N, P, or As, where +5 is also common.

Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Modern Periodic Law and Present Form - Long Form Periodic Table

Which group 2 element forms a hydroxide with the lowest solubility in water?

Solubility of group 2 hydroxides increases down the group due to decreasing lattice energy. Be(OH)2 has the lowest solubility due to Be’s small size and high charge density.

Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Modern Periodic Law and Present Form - Long Form Periodic Table

Which group 15 element forms a trichloride with the highest covalent character?

Covalent character (Fajans’ rule) increases with smaller size and higher charge density. NCl₃ (N, smallest) has the highest covalent character among N, P, As, and Sb trichlorides.

Ref: NCERT Class 11 Chemistry > Chapter 3: Classification of Elements and Periodicity in Properties > Topic: Modern Periodic Law and Present Form - Long Form Periodic Table